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JEE Advanced 2025 Paper 1 · Chemistry · Redox Reactions and Titrations · medium

Match each reaction in List-I with the oxidation state of the element named in List-II. List-I (P) Cu + dilute HNO3: nitrogen in the colourless gas…

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Match each reaction in List-I with the oxidation state of the element named in List-II.

List-I
(P) Cu\mathrm{Cu} + dilute HNO3\mathrm{HNO_3}: nitrogen in the colourless gas evolved, which turns brown in air
(Q) Cu\mathrm{Cu} + concentrated HNO3\mathrm{HNO_3}: nitrogen in the brown gas evolved
(R) Zn\mathrm{Zn} + very dilute HNO3\mathrm{HNO_3}: nitrogen in the ammonium salt formed
(S) Cl2\mathrm{Cl_2} + hot concentrated NaOH\mathrm{NaOH}: chlorine in the oxoanion formed (other than chloride)

List-II
(1) +4+4
(2) +1+1
(3) +5+5
(4) −3-3
(5) +2+2
  1. A. P→5, Q→1, R→4, S→3
  2. B. P→1, Q→5, R→4, S→3
  3. C. P→5, Q→1, R→4, S→2
  4. D. P→2, Q→1, R→3, S→4
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Answer: (A) P→5, Q→1, R→4, S→3

P: 3Cu+8HNO3(dil)→3Cu(NO3)2+2NO+4H2O3\mathrm{Cu}+8\mathrm{HNO_3}(\text{dil})\to3\mathrm{Cu(NO_3)_2}+2\mathrm{NO}+4\mathrm{H_2O}. The gas is NO\mathrm{NO}, nitrogen +2+2 (5), which becomes brown NO2\mathrm{NO_2} in air. Q: Cu+4HNO3(conc)→Cu(NO3)2+2NO2+2H2O\mathrm{Cu}+4\mathrm{HNO_3}(\text{conc})\to\mathrm{Cu(NO_3)_2}+2\mathrm{NO_2}+2\mathrm{H_2O}, brown NO2\mathrm{NO_2}, nitrogen +4+4 (1). R: 4Zn+10HNO3→4Zn(NO3)2+NH4NO3+3H2O4\mathrm{Zn}+10\mathrm{HNO_3}\to4\mathrm{Zn(NO_3)_2}+\mathrm{NH_4NO_3}+3\mathrm{H_2O}, the ammonium ion with nitrogen at −3-3 (4). S: 3Cl2+6OH−→Δ5Cl−+ClO3−+3H2O3\mathrm{Cl_2}+6\mathrm{OH^-}\xrightarrow{\Delta}5\mathrm{Cl^-}+\mathrm{ClO_3^-}+3\mathrm{H_2O}, chlorate with chlorine at +5+5 (3). The value +1+1 (hypochlorite) is the product with cold dilute alkali and is not used. Option B interchanges P and Q, C assigns hypochlorite to S, and D uses wrong gases. The correct code is option A. Each List-II value is used at most once and each List-I entry has exactly one match.
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