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JEE Advanced 2023 Paper 2 · Physics · Work, Energy and Power · medium

Two identical metal blocks, each of heat capacity C=1.5 kJ K^-1 (independent of temperature), are at 400 K and 100 K. A reversible heat engine…

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Two identical metal blocks, each of heat capacity C=1.5 kJ K−1C=1.5\ \mathrm{kJ\,K^{-1}} (independent of temperature), are at 400 K400\ \mathrm{K} and 100 K100\ \mathrm{K}. A reversible heat engine operates between them until the two blocks reach the same temperature; no other heat exchange occurs. Which of the following statements is/are correct?
  1. A. The common final temperature is 250 K250\ \mathrm{K}.
  2. B. The total work delivered by the engine is 150 kJ150\ \mathrm{kJ}.
  3. C. The heat rejected by the engine into the colder block is 300 kJ300\ \mathrm{kJ}.
  4. D. The average efficiency of the engine over the whole process equals the initial Carnot efficiency, 75%75\%.
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Answer: B

For a reversible process the entropy of the two blocks together is unchanged: Cln⁡Tf400+Cln⁡Tf100=0C\ln\dfrac{T_f}{400}+C\ln\dfrac{T_f}{100}=0, so Tf=400×100=200 KT_f=\sqrt{400\times100}=200\ \mathrm{K}, not the contact-mixing value 250 K250\ \mathrm{K}: (A) incorrect. Heat drawn from the hot block: Qh=C(400−200)=300 kJQ_h=C(400-200)=300\ \mathrm{kJ}. Heat delivered to the cold block: Qc=C(200−100)=150 kJQ_c=C(200-100)=150\ \mathrm{kJ}. Work W=Qh−Qc=150 kJW=Q_h-Q_c=150\ \mathrm{kJ} (equivalently C(T1+T2−2T1T2)C(T_1+T_2-2\sqrt{T_1T_2})): (B) correct, (C) incorrect since 300 kJ300\ \mathrm{kJ} is QhQ_h. Overall efficiency =150/300=50%=150/300=50\%; the Carnot efficiency 75%75\% holds only at the start, and it falls as the temperature difference shrinks: (D) incorrect.
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