Numerical answer
One mole of an ideal diatomic gas (, ) at is compressed reversibly and adiabatically to one-eighth of its initial volume. It is then allowed to expand reversibly and isothermally, at the final temperature of the compression, back to its original volume. Taking and , the net work done by the gas over the two steps, in kJ, is ______. (Give the answer correct to two decimal places.)
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Answer: 3.83
Step 1 is a reversible adiabatic compression, so is constant: . Work done on the gas in this step equals the rise in internal energy, , so the work done by the gas is . Step 2 is an isothermal reversible expansion at from to , a volume ratio of . The work done by the gas is . Net work done by the gas is . The positive sign means the isothermal expansion at the higher temperature delivers more work than the adiabatic compression consumed; the extra energy comes from the heat absorbed during the isothermal step. The gas ends at its original volume but at .
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