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JEE Advanced 2020 Paper 2 · Chemistry · Chemical Thermodynamics · hard

One mole of an ideal diatomic gas (CV=5/2R, γ=1.4) at 300 K is compressed reversibly and adiabatically to one-eighth of its initial volume. It is…

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One mole of an ideal diatomic gas (CV=52RC_V=\tfrac52R, γ=1.4\gamma=1.4) at 300 K300\ \mathrm{K} is compressed reversibly and adiabatically to one-eighth of its initial volume. It is then allowed to expand reversibly and isothermally, at the final temperature of the compression, back to its original volume. Taking R=8.314 J mol−1K−1R=8.314\ \mathrm{J\,mol^{-1}K^{-1}} and 80.4=2.2978^{0.4}=2.297, the net work done by the gas over the two steps, in kJ, is ______. (Give the answer correct to two decimal places.)
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Answer: 3.83

Step 1 is a reversible adiabatic compression, so TVγ−1TV^{\gamma-1} is constant: T2=300×80.4=689.2 KT_2=300\times8^{0.4}=689.2\ \mathrm{K}. Work done on the gas in this step equals the rise in internal energy, W1=CVΔT=2.5×8.314×(689.2−300)=8090 JW_1=C_V\Delta T=2.5\times8.314\times(689.2-300)=8090\ \mathrm{J}, so the work done by the gas is −8.09 kJ-8.09\ \mathrm{kJ}. Step 2 is an isothermal reversible expansion at 689.2 K689.2\ \mathrm{K} from V0/8V_0/8 to V0V_0, a volume ratio of 88. The work done by the gas is W2=RT2ln⁡8=8.314×689.2×2.0794=11916 J=11.92 kJW_2=RT_2\ln8=8.314\times689.2\times2.0794=11916\ \mathrm{J}=11.92\ \mathrm{kJ}. Net work done by the gas is 11.92−8.09=3.83 kJ11.92-8.09=3.83\ \mathrm{kJ}. The positive sign means the isothermal expansion at the higher temperature delivers more work than the adiabatic compression consumed; the extra energy comes from the heat absorbed during the isothermal step. The gas ends at its original volume but at 689.2 K689.2\ \mathrm{K}.
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