PrepRung

JEE Advanced 2022 Paper 1 · Chemistry · d- and f-Block Elements and Metallurgy · medium

Regarding the isolation of metals from their ores, choose the correct statement(s).

One or more options correct

Regarding the isolation of metals from their ores, choose the correct statement(s).
  1. A. In the Hall–Héroult process, cryolite is added to alumina to lower the melting point of the electrolytic mixture and to improve its conductivity, and the graphite anode is gradually consumed as CO\mathrm{CO} and CO2\mathrm{CO_2}
  2. B. In the Mond process, impure nickel is converted at about 330330–350 K350\ \mathrm{K} into volatile Ni(CO)4\mathrm{Ni(CO)_4}, which decomposes at about 450450–470 K470\ \mathrm{K} to give pure nickel
  3. C. In the upper, cooler region of a blast furnace, Fe2O3\mathrm{Fe_2O_3} is reduced mainly by solid carbon in direct contact with the ore
  4. D. In the extraction of copper from copper pyrites, silica is added to convert FeO\mathrm{FeO} into FeSiO3\mathrm{FeSiO_3} slag, and in the Bessemer converter partly formed Cu2O\mathrm{Cu_2O} reacts with Cu2S\mathrm{Cu_2S} to give copper and SO2\mathrm{SO_2}
Show answer and solution

Answer: A, B, D

A is correct: cryolite Na3AlF6\mathrm{Na_3AlF_6} lowers the melting point from about 23002300 K to about 12001200 K and raises conductivity; oxygen liberated at the carbon anode burns it to CO\mathrm{CO}/CO2\mathrm{CO_2}. B is correct: the Mond process uses the reversible formation Ni+4CO⇌Ni(CO)4\mathrm{Ni+4CO\rightleftharpoons Ni(CO)_4}, forward at low temperature and backward at high temperature. C is incorrect: in the cooler upper zone the reducing agent is CO\mathrm{CO} (indirect reduction, Fe2O3→Fe3O4→FeO\mathrm{Fe_2O_3\to Fe_3O_4\to FeO}), whereas direct reduction by carbon occurs in the hotter lower zone. D is correct: FeO+SiO2→FeSiO3\mathrm{FeO+SiO_2\to FeSiO_3} removes iron as slag, and 2Cu2O+Cu2S→6Cu+SO2\mathrm{2Cu_2O+Cu_2S\to6Cu+SO_2} is the self-reduction in the converter. Hence A, B and D.
Report a mistake

Original question written in the JEE Advanced 2022 Paper 1 pattern and checked twice for the correct answer. Not an official question paper. How we write and check questions · Corrections policy · Report a mistake