Numerical answer
of aqueous ( at ) is mixed with of and the resulting solution is diluted with water to . Neglect the contribution of water autoionisation to in the buffer. What is the pH of the final solution at (take )?
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Answer: 8
Moles of and moles of . The strong acid converts of into , leaving and , a basic buffer. Dilution to changes both concentrations by the same factor (, ), so the ratio is unaffected. Then , so and . A solution of this kind is mildly basic; is still large enough compared with from water that the approximation is acceptable for the stated answer. The pH is 8.
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