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JEE Advanced 2024 Paper 1 · Physics · Thermodynamics and Kinetic Theory of Gases · medium

One mole of a monatomic ideal gas undergoes a cyclic process A→ B→ C→ A. Process A→ B is isochoric, raising the pressure from P0 to 3P0 at volume V0.…

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One mole of a monatomic ideal gas undergoes a cyclic process A→B→C→AA\to B\to C\to A. Process A→BA\to B is isochoric, raising the pressure from P0P_0 to 3P03P_0 at volume V0V_0. Process B→CB\to C is an isothermal expansion until the pressure falls back to P0P_0. Process C→AC\to A is an isobaric compression at pressure P0P_0. The efficiency of this cycle, defined as net work done by the gas divided by the total heat absorbed, is closest to (ln⁡3=1.0986\ln 3=1.0986)
  1. A. 52.3%52.3\%
  2. B. 39.3%39.3\%
  3. C. 43.2%43.2\%
  4. D. 20.6%20.6\%
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Answer: (D) 20.6%20.6\%

Heat is absorbed in A→BA\to B and B→CB\to C; it is rejected in C→AC\to A. For A→BA\to B: QAB=CVΔT=32 Δ(PV)=32(3P0V0−P0V0)=3P0V0Q_{AB}=C_V\Delta T=\tfrac32\,\Delta(PV)=\tfrac32(3P_0V_0-P_0V_0)=3P_0V_0. For B→CB\to C (isothermal, TB=TCT_B=T_C): PCVC=3P0V0P_CV_C=3P_0V_0 so VC=3V0V_C=3V_0 and QBC=WBC=3P0V0ln⁡3Q_{BC}=W_{BC}=3P_0V_0\ln 3. In C→AC\to A the work done by the gas is P0(V0−3V0)=−2P0V0P_0(V_0-3V_0)=-2P_0V_0. Net work W=3P0V0ln⁡3−2P0V0=1.2958 P0V0W=3P_0V_0\ln3-2P_0V_0=1.2958\,P_0V_0. Heat absorbed Qin=3P0V0+3P0V0ln⁡3=6.2958 P0V0Q_{in}=3P_0V_0+3P_0V_0\ln 3=6.2958\,P_0V_0. Hence η=1.2958/6.2958=0.2058≈20.6%\eta=1.2958/6.2958=0.2058\approx 20.6\%. Because the cycle contains an isothermal arc, ΔU=0\Delta U=0 over B→CB\to C, so all heat absorbed there becomes work; the isobaric leg is the only place heat leaves the gas. The value 52.3%52.3\% ignores the compression work, 39.3%39.3\% divides by only the isothermal heat, and 43.2%43.2\% divides by 3P0V03P_0V_0 alone.
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