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JEE Advanced 2024 Paper 2 · Physics · Thermodynamics and Kinetic Theory of Gases · hard

One mole of a monatomic ideal gas undergoes a quasi-static process described by P=P0(4-V/V0) as its volume increases from V0 to 3V0. The gas absorbs…

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One mole of a monatomic ideal gas undergoes a quasi-static process described by P=P0(4−VV0)P=P_0\left(4-\dfrac{V}{V_0}\right) as its volume increases from V0V_0 to 3V03V_0. The gas absorbs heat from the surroundings during the part of the process from V=V0V=V_0 up to V=V∗V=V^{*} and rejects heat for V∗<V≤3V0V^{*}<V\le 3V_0. The value of V∗V^{*} is
  1. A. 2V02V_0
  2. B. 52V0\dfrac{5}{2}V_0
  3. C. 3V03V_0
  4. D. 73V0\dfrac{7}{3}V_0
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Answer: (B) 52V0\dfrac{5}{2}V_0

Let x=V/V0x=V/V_0. For a monatomic gas dU=32 d(PV)dU=\tfrac32\,d(PV) and dW=P dVdW=P\,dV, so dQ=32 d(PV)+P dVdQ=\tfrac32\,d(PV)+P\,dV. Here PV=P0V0 (4x−x2)PV=P_0V_0\,(4x-x^2), so d(PV)=P0V0(4−2x) dxd(PV)=P_0V_0(4-2x)\,dx and P dV=P0V0(4−x) dxP\,dV=P_0V_0(4-x)\,dx. Therefore dQ=P0V0[32(4−2x)+(4−x)]dx=P0V0 (10−4x) dxdQ=P_0V_0\left[\tfrac32(4-2x)+(4-x)\right]dx=P_0V_0\,(10-4x)\,dx. Heat is absorbed while 10−4x>010-4x>0, i.e. up to x=52x=\tfrac52, beyond which dQ<0dQ<0 and heat is rejected. The net heat absorbed from x=1x=1 to x=52x=\tfrac52 is 92P0V0\tfrac92P_0V_0. Note that x=2x=2 (option A) is where PVPV, and hence the temperature, is maximum; the gas still absorbs heat after that point because the work done exceeds the fall in internal energy. At x=3x=3 the process ends, but heat is already being rejected before it. The correct option is (B).
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