One or more options correct
Which of the following reactions is/are correctly described?
- A. Benzaldehyde heated with excess formaldehyde in concentrated gives benzyl alcohol and sodium formate (crossed Cannizzaro reaction).
- B. Acetophenone with gives iodoform and sodium benzoate.
- C. Pentan-3-one on warming with gives a yellow precipitate of iodoform.
- D. Benzaldehyde in dilute undergoes self aldol condensation to give cinnamaldehyde.
Show answer and solution
Answer: A, B
Option A: benzaldehyde has no -hydrogen and neither does formaldehyde; in the crossed Cannizzaro reaction the more reactive, unhindered formaldehyde adds hydroxide and donates hydride, so it is oxidised to formate, while benzaldehyde accepts the hydride and is reduced to , so A is correct. Option B: is a methyl ketone, so haloform cleavage gives and , and B is correct. Option C: pentan-3-one, , has no group (the carbonyl is flanked by ethyl groups), so it gives no iodoform; C is wrong. Option D: benzaldehyde lacks -hydrogens and cannot form an enolate, so it cannot undergo self aldol condensation. Cinnamaldehyde would need acetaldehyde as the enolisable partner in a crossed aldol reaction, so D is wrong.
Saved on this device. Sign in or create a free account to keep it on every device.