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JEE Advanced 2025 Paper 2 · Chemistry · Chemical Bonding and Molecular Structure · medium

Consider the species XeO3, XeF6, XeOF4, XeO2F2, BrF5, SF4, XeF4, XeF2, ICl4^-, ClF3, XeO4 and IF7. The number of species in which the central atom…

Numerical answer

Consider the species XeO3\mathrm{XeO_3}, XeF6\mathrm{XeF_6}, XeOF4\mathrm{XeOF_4}, XeO2F2\mathrm{XeO_2F_2}, BrF5\mathrm{BrF_5}, SF4\mathrm{SF_4}, XeF4\mathrm{XeF_4}, XeF2\mathrm{XeF_2}, ICl4−\mathrm{ICl_4^-}, ClF3\mathrm{ClF_3}, XeO4\mathrm{XeO_4} and IF7\mathrm{IF_7}. The number of species in which the central atom has exactly one lone pair and is sp3dsp^3d or sp3d2sp^3d^2 hybridised is ____.
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Answer: 4

Steric number =12(V+M−c)=\frac12(V+M-c), where VV is the number of valence electrons of the central atom, MM the number of monovalent atoms (oxygen, being doubly bonded, is not counted) and cc the charge; lone pairs == steric number −- number of σ\sigma bonds. XeO3\mathrm{XeO_3}: 44, 1 lone pair, sp3sp^3. XeF6\mathrm{XeF_6}: 77, 1 lone pair, sp3d3sp^3d^3. XeOF4\mathrm{XeOF_4}: 66, 1 lone pair, sp3d2sp^3d^2. XeO2F2\mathrm{XeO_2F_2}: 55, 1 lone pair, sp3dsp^3d. BrF5\mathrm{BrF_5}: 66, 1 lone pair, sp3d2sp^3d^2. SF4\mathrm{SF_4}: 55, 1 lone pair, sp3dsp^3d. XeF4\mathrm{XeF_4}, ICl4−\mathrm{ICl_4^-} and ClF3\mathrm{ClF_3} have two lone pairs; XeF2\mathrm{XeF_2} has three; XeO4\mathrm{XeO_4} and IF7\mathrm{IF_7} have none. Species with one lone pair and sp3dsp^3d or sp3d2sp^3d^2: XeOF4\mathrm{XeOF_4}, XeO2F2\mathrm{XeO_2F_2}, BrF5\mathrm{BrF_5}, SF4\mathrm{SF_4}, so the answer is 44.
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