One or more options correct
Choose the correct statement(s) about s-block compounds.
- A. On strong heating, gives , and , whereas gives and
- B. Potassium superoxide is diamagnetic, since the superoxide ion has all its electrons paired
- C. Solid is a chain polymer in which each Be atom is -hybridised and trigonal planar
- D. Sodium peroxide is paramagnetic because of the unpaired electrons in the peroxide ion
Show answer and solution
Answer: A
A is correct: the small, strongly polarising stabilises the oxide and the nitrate decomposes as , while the sodium and potassium nitrates stop at the nitrite. B is incorrect: the superoxide ion has valence electrons, three of them in the level, so one electron is unpaired; it is paramagnetic with bond order . C is incorrect: in the chain of solid each Be is bonded to four bridging chlorine atoms (3c-4e type bonding), tetrahedral and hybridised; the planar picture applies to the gas-phase monomer. D is incorrect: the peroxide ion has bond order and all electrons paired in , so it is diamagnetic. Only A is correct.
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