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JEE Main 2017 · Physics · Calorimetry and Heat Transfer · hard

100 g of ice at -10^circC is added to 200 g of water at 40^circC in an insulated container of negligible heat capacity. Specific heat of ice = 0.5…

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100 g100\ \mathrm{g} of ice at −10∘C-10^\circ\mathrm{C} is added to 200 g200\ \mathrm{g} of water at 40∘C40^\circ\mathrm{C} in an insulated container of negligible heat capacity. Specific heat of ice =0.5 cal g−1 ∘C−1= 0.5\ \mathrm{cal\,g^{-1}\,{}^\circ C^{-1}}, specific heat of water =1 cal g−1 ∘C−1= 1\ \mathrm{cal\,g^{-1}\,{}^\circ C^{-1}}, latent heat of fusion =80 cal g−1= 80\ \mathrm{cal\,g^{-1}}. When equilibrium is reached, the mass of ice that remains is
  1. A. 6.25 g6.25\ \mathrm{g}
  2. B. 0 g0\ \mathrm{g}
  3. C. 12.5 g12.5\ \mathrm{g}
  4. D. 25 g25\ \mathrm{g}
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Answer: (A) 6.25 g6.25\ \mathrm{g}

Heat available from water cooling to 0∘C0^\circ\mathrm{C}: 200×1×40=8000 cal200\times1\times40 = 8000\ \mathrm{cal}. Heat needed to warm the ice to 0∘C0^\circ\mathrm{C}: 100×0.5×10=500 cal100\times0.5\times10 = 500\ \mathrm{cal}. Melting all the ice would need a further 100×80=8000 cal100\times80 = 8000\ \mathrm{cal}, which exceeds the remaining 7500 cal7500\ \mathrm{cal}. So the final temperature is 0∘C0^\circ\mathrm{C} with some ice left. Ice melted =7500/80=93.75 g= 7500/80 = 93.75\ \mathrm{g}, so the ice remaining is 100−93.75=6.25 g100 - 93.75 = 6.25\ \mathrm{g}. A common error is to forget the 500 cal500\ \mathrm{cal} for warming the ice and answer 0 g0\ \mathrm{g} or 12.5 g12.5\ \mathrm{g}.
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