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JEE Advanced 2022 Paper 1 · Physics · Atoms, Nuclei and Dual Nature of Radiation · medium

A hydrogen-like ion is in the excited state given in List-I. Match each with the energy needed to remove its electron completely from that state, in…

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A hydrogen-like ion is in the excited state given in List-I. Match each with the energy needed to remove its electron completely from that state, in List-II (take the hydrogen ground-state energy as −13.6 eV-13.6\ \mathrm{eV}).

List-I: (P) H\mathrm{H} in n=2n=2; (Q) He+\mathrm{He^{+}} in n=3n=3; (R) Li2+\mathrm{Li^{2+}} in n=2n=2; (S) Be3+\mathrm{Be^{3+}} in n=3n=3.

List-II (in eV): (1) 3.403.40; (2) 6.046.04; (3) 24.1824.18; (4) 30.6030.60; (5) 13.6013.60.
  1. A. P→1, Q→2, R→4, S→3
  2. B. P→1, Q→2, R→3, S→4
  3. C. P→5, Q→2, R→4, S→3
  4. D. P→1, Q→5, R→4, S→2
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Answer: (A) P→1, Q→2, R→4, S→3

Ionisation energy from level nn is 13.6 Z2/n213.6\,Z^2/n^2. (P) 13.6/4=3.4013.6/4=3.40 (1). (Q) 13.6×4/9=6.0413.6\times4/9=6.04 (2). (R) 13.6×9/4=30.6013.6\times9/4=30.60 (4). (S) 13.6×16/9=24.1813.6\times16/9=24.18 (3). So P→1, Q→2, R→4, S→3. Entry (5) 13.6013.60 is a distractor for an ion with Z/n=1Z/n=1, which none of these has.
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