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JEE Advanced 2024 Paper 1 · Physics · Atoms, Nuclei and Dual Nature of Radiation · easy

A radioactive nuclide A of half-life 3 h decays to a radioactive nuclide B of half-life 6 h, which decays to a stable nuclide C. At t=0 a sample…

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A radioactive nuclide AA of half-life 3 h3\ \mathrm{h} decays to a radioactive nuclide BB of half-life 6 h6\ \mathrm{h}, which decays to a stable nuclide CC. At t=0t=0 a sample contains N0N_0 nuclei of AA and none of BB or CC. At the instant when the number of BB nuclei is maximum, the number of BB nuclei is
  1. A. N0/2N_0/2
  2. B. N0/4N_0/4
  3. C. N0/3N_0/3
  4. D. 3N0/83N_0/8
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Answer: (A) N0/2N_0/2

The number of BB nuclei is NB(t)=λAN0λB−λA(e−λAt−e−λBt)N_B(t)=\dfrac{\lambda_AN_0}{\lambda_B-\lambda_A}\left(e^{-\lambda_At}-e^{-\lambda_Bt}\right) with λA=2λB\lambda_A=2\lambda_B since the half-life of AA is half that of BB. Hence NB=2N0(e−λBt−e−2λBt)N_B=2N_0\left(e^{-\lambda_Bt}-e^{-2\lambda_Bt}\right). It is maximum when dNB/dt=0dN_B/dt=0, i.e. when λANA=λBNB\lambda_AN_A=\lambda_BN_B, equivalently when e−λBt=1/2e^{-\lambda_Bt}=1/2, which occurs at t=6 ht=6\ \mathrm{h} (one half-life of BB). Putting x=e−λBt=12x=e^{-\lambda_Bt}=\tfrac12 gives NB=2N0(12−14)=N0/2N_B=2N_0\left(\tfrac12-\tfrac14\right)=N_0/2. As a check, NA=N0e−λAt=N0/4N_A=N_0e^{-\lambda_At}=N_0/4 and NB/NA=λA/λB=2N_B/N_A=\lambda_A/\lambda_B=2, consistent with the transient-equilibrium condition. At that instant the activities of A and B are equal, so the activity plot of B crosses that of A at its peak. N0/4N_0/4 is the number of AA nuclei at that instant, a common slip.
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