Numerical answer
A sample of ions, all in the ground state, is bombarded with electrons of kinetic energy . Assume that an electron can transfer any part of its energy to an ion in an inelastic collision. Every ion that is excited then de-excites by emitting photons, and all possible spectral lines (between all pairs of levels reachable) are observed. Take the ground-state energy of hydrogen as . The photons from these lines fall on a metal of work function . The number of distinct spectral lines whose photons can eject photoelectrons from this metal is
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Answer: 4
For () the levels are . The excitation energies from are (), (), () and (). Electrons of can therefore excite ions up to but not . The lines among the levels to are six in number, with energies (), (), (), (), () and (). Photoemission requires photon energy greater than the work function . This is satisfied by , , and but not by or . So lines can eject photoelectrons.
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