One or more options correct
Consider the nickel(II) complexes , and (atomic number of Ni ). The correct statement(s) is(are)
- A. is tetrahedral and paramagnetic with two unpaired electrons
- B. is square planar and diamagnetic
- C. is tetrahedral and paramagnetic because Ni is present in the zero oxidation state with a configuration
- D. and have the same spin-only magnetic moment
Show answer and solution
Answer: A, B
Ni(II) is . With the weak-field ligand the complex is tetrahedral; in the tetrahedral field the configuration leaves two unpaired electrons, so it is paramagnetic and (A) is correct. The strong-field ligand forces pairing of all eight electrons in four orbitals, freeing one orbital for hybridisation, so is square planar and diamagnetic and (B) is correct. In the strong-field CO ligands push the two electrons into , giving nickel(0); it is tetrahedral but has no unpaired electron, so it is diamagnetic and (C) is wrong. Since has two unpaired electrons ( BM) while has none, (D) is wrong.
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