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JEE Advanced 2019 Paper 2 · Physics · Thermodynamics and Kinetic Theory of Gases · hard

One mole of a monatomic ideal gas undergoes a cyclic process A→ B→ C→ A in the P-V plane. A is the state (V0,P0) with temperature T0=P0V0/R. The…

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One mole of a monatomic ideal gas undergoes a cyclic process A→B→C→AA\to B\to C\to A in the PP-VV plane. AA is the state (V0,P0)(V_0,P_0) with temperature T0=P0V0/RT_0=P_0V_0/R. The process ABAB is an isobaric expansion to volume 2V02V_0, BCBC is an isochoric decrease of pressure to P0/2P_0/2, and CACA is a straight line in the PP-VV plane that returns the gas to AA. Which of the following statement(s) is(are) correct?
  1. A. The net work done by the gas in one cycle is 14P0V0\tfrac14P_0V_0.
  2. B. The highest temperature attained by the gas during the process CACA is 98T0\tfrac98T_0.
  3. C. The efficiency of the cycle is exactly 10%10\%.
  4. D. Although the net heat exchanged in the process CACA is negative, the gas absorbs heat during a part of CACA.
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Answer: A, B, D

The cycle is a right triangle with base V0V_0 and height P0/2P_0/2, traversed clockwise, so W=12V0⋅P02=14P0V0W=\tfrac12 V_0\cdot\tfrac{P_0}{2}=\tfrac14P_0V_0 and (A) is correct. On CACA, P=32P0−P0V2V0P=\tfrac32P_0-\dfrac{P_0V}{2V_0}, so PVPV has its maximum at V=32V0V=\tfrac32V_0 with value 98P0V0\tfrac98P_0V_0, giving Tmax⁡=98T0T_{\max}=\tfrac98T_0 on this segment and (B) is correct. Heat in: QAB=52P0V0Q_{AB}=\tfrac52P_0V_0. On CACA, dQ=dU+P dV∝(3.75−2V/V0) dVdQ=dU+P\,dV\propto(3.75-2V/V_0)\,dV changes sign at V=1.875V0V=1.875V_0, so the gas absorbs a small positive heat 164P0V0\tfrac{1}{64}P_0V_0 near CC although the net QCA=−34P0V0Q_{CA}=-\tfrac34P_0V_0; (D) is correct. Hence η=0.252.5+0.0156≈9.94%\eta=\dfrac{0.25}{2.5+0.0156}\approx9.94\%, not exactly 10%10\%; (C) is wrong. Answer: A, B, D.
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