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JEE Advanced 2020 Paper 2 · Physics · Thermodynamics and Kinetic Theory of Gases · hard

One mole of a monatomic ideal gas executes a rectangular cycle on a P–V diagram: from a(P0,V0) isochorically to b(2P0,V0), then isobarically to…

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One mole of a monatomic ideal gas executes a rectangular cycle on a PP–VV diagram: from a(P0,V0)a(P_0,V_0) isochorically to b(2P0,V0)b(2P_0,V_0), then isobarically to c(2P0,2V0)c(2P_0,2V_0), then isochorically to d(P0,2V0)d(P_0,2V_0), then isobarically back to aa. Choose the correct statement(s).
  1. A. The net work done by the gas in one cycle is P0V0P_0V_0.
  2. B. The efficiency of the cycle is 2/132/13.
  3. C. The heat rejected during d→ad\to a is 2.5 P0V02.5\,P_0V_0.
  4. D. The efficiency is more than half that of a Carnot engine working between the extreme temperatures of the cycle.
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Answer: A, B, C

Temperatures in units of T0=P0V0/RT_0=P_0V_0/R are a:1, b:2, c:4, d:2a:1,\ b:2,\ c:4,\ d:2. Net work is the rectangle area (2P0−P0)(2V0−V0)=P0V0(2P_0-P_0)(2V_0-V_0)=P_0V_0: (A) true. Heat absorbed: a→ba\to b is CVΔT=32R(T0)=1.5P0V0C_V\Delta T=\tfrac32R(T_0)=1.5P_0V_0 and b→cb\to c is CPΔT=52R(2T0)=5P0V0C_P\Delta T=\tfrac52R(2T_0)=5P_0V_0, so Qin=6.5P0V0Q_{in}=6.5P_0V_0 and η=1/6.5=2/13≈15.4%\eta=1/6.5=2/13\approx15.4\%: (B) true. In d→ad\to a the gas is compressed isobarically from 2T02T_0 to T0T_0, rejecting 52R T0=2.5P0V0\tfrac52R\,T_0=2.5P_0V_0: (C) true. The extreme temperatures are T0T_0 and 4T04T_0, so ηCarnot=0.75\eta_{Carnot}=0.75; half of it is 0.3750.375, which exceeds 0.1540.154: (D) false. As a cross-check, the heat taken in is 6.5P0V06.5P_0V_0 and the heat rejected is 3P0V0+2.5P0V0=5.5P0V03P_0V_0+2.5P_0V_0=5.5P_0V_0; their difference is the net work P0V0P_0V_0, in agreement with the area of the loop on the diagram.
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