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JEE Main 2024 · Chemistry · s-Block, p-Block Elements and Hydrogen · easy

The total number of P-OH groups present in H3PO2, H3PO3, H3PO4 and H4P2O7 taken together is

Numerical answer

The total number of P−OH\mathrm{P{-}OH} groups present in H3PO2\mathrm{H_3PO_2}, H3PO3\mathrm{H_3PO_3}, H3PO4\mathrm{H_3PO_4} and H4P2O7\mathrm{H_4P_2O_7} taken together is
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Answer: 10

Only the P−OH\mathrm{P{-}OH} hydrogens are ionisable; P-H hydrogens are not. H3PO2\mathrm{H_3PO_2} (hypophosphorous): two P-H, one P-OH =1=1. H3PO3\mathrm{H_3PO_3}: one P-H, two P-OH =2=2. H3PO4\mathrm{H_3PO_4}: three P-OH =3=3. H4P2O7\mathrm{H_4P_2O_7} (pyrophosphoric acid, two P atoms joined through a P-O-P bridge): each P carries two P-OH =4=4. Total =1+2+3+4=10=1+2+3+4=10.
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