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JEE Advanced 2016 Paper 1 · Chemistry · Chemical Bonding and Molecular Structure · easy

Among the following species, how many are both square planar in shape and have a zero dipole moment? XeF4, SF4, ICl4^-, [Ni(CN)4]^2-, [NiCl4]^2-…

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Among the following species, how many are both square planar in shape and have a zero dipole moment? XeF4\mathrm{XeF_4}, SF4\mathrm{SF_4}, ICl4−\mathrm{ICl_4^-}, [Ni(CN)4]2−[\mathrm{Ni(CN)_4}]^{2-}, [NiCl4]2−[\mathrm{NiCl_4}]^{2-}, BrF5\mathrm{BrF_5}, ClF3\mathrm{ClF_3}, [PtCl4]2−[\mathrm{PtCl_4}]^{2-}
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Answer: 4

Examine each species using VSEPR or ligand-field arguments. XeF4\mathrm{XeF_4}: four bond pairs and two lone pairs, octahedral electron geometry with the lone pairs trans, so square planar and non-polar. SF4\mathrm{SF_4}: one lone pair, see-saw shape, polar. ICl4−\mathrm{ICl_4^-}: iodine has four bond pairs and two lone pairs, square planar, non-polar. [Ni(CN)4]2−[\mathrm{Ni(CN)_4}]^{2-}: d8d^8 with strong-field CN−\mathrm{CN^-}, dsp2dsp^2 square planar, symmetric, non-polar. [NiCl4]2−[\mathrm{NiCl_4}]^{2-}: weak-field chloride, sp3sp^3 tetrahedral, so not square planar. BrF5\mathrm{BrF_5}: square pyramidal, polar. ClF3\mathrm{ClF_3}: T-shaped, polar. [PtCl4]2−[\mathrm{PtCl_4}]^{2-}: 5d85d^8 platinum(II), always square planar and non-polar. Four species qualify: XeF4\mathrm{XeF_4}, ICl4−\mathrm{ICl_4^-}, [Ni(CN)4]2−[\mathrm{Ni(CN)_4}]^{2-} and [PtCl4]2−[\mathrm{PtCl_4}]^{2-}.
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