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JEE Advanced 2017 Paper 1 · Chemistry · Chemical Bonding and Molecular Structure · easy

The total number of lone pairs of electrons present on the central atoms of the species XeF2, XeF4, XeO3, XeOF4 and ICl4^- taken together is ____ .

Numerical answer

The total number of lone pairs of electrons present on the central atoms of the species XeF2\mathrm{XeF_2}, XeF4\mathrm{XeF_4}, XeO3\mathrm{XeO_3}, XeOF4\mathrm{XeOF_4} and ICl4−\mathrm{ICl_4^-} taken together is ____ .
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Answer: 9

For each central atom, lone pairs =12=\tfrac12(valence electrons of the atom, adjusted for charge, minus the electrons it commits to bonds with the surrounding atoms; a double bond commits two electrons). XeF2\mathrm{XeF_2}: Xe has 88 valence electrons and commits 22 to two Xe-F bonds, leaving 66, i.e. 33 lone pairs (linear). XeF4\mathrm{XeF_4}: 8−4=48-4=4 electrons, 22 lone pairs (square planar). XeO3\mathrm{XeO_3}: three Xe=O bonds commit 66 electrons, leaving 22, i.e. 11 lone pair (trigonal pyramidal). XeOF4\mathrm{XeOF_4}: four Xe-F single bonds and one Xe=O bond commit 4+2=64+2=6 electrons, leaving 11 lone pair (square pyramidal). ICl4−\mathrm{ICl_4^-}: 7+1=87+1=8 valence electrons, 44 committed to I-Cl bonds, so 22 lone pairs (square planar). The total number of lone pairs on the central atoms is 3+2+1+1+2=93+2+1+1+2=9.
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