JEE Advanced 2016 Paper 1 · Chemistry · Chemical Bonding and Molecular Structure · medium
Using molecular orbital theory for homonuclear diatomic species of second-period elements, choose the correct statement(s).
One or more options correct
Using molecular orbital theory for homonuclear diatomic species of second-period elements, choose the correct statement(s).
A.O22− has bond order 1 and is diamagnetic.
B.C2 is paramagnetic because of two unpaired electrons in π orbitals.
C.B2 has bond order 2 and is diamagnetic.
D.N2+ has a shorter bond length than N2.
Show answer and solution
Answer:A
(A) Correct. O22− has 14 valence electrons: σ2s2σ2s∗2σ2p2π2p4π2p∗4, giving bond order 28−6=1 with all electrons paired. (B) Incorrect. C2 has 8 valence electrons with the π2p orbitals lying below σ2p; the configuration σ2s2σ2s∗2π2p4 has all electrons paired, bond order 2, so it is diamagnetic. (C) Incorrect. B2 has 6 valence electrons, σ2s2σ2s∗2π2p1π2p1 with parallel spins, so bond order is 1 and it is paramagnetic. (D) Incorrect. Removing a bonding electron lowers the bond order from 3 (in N2) to 2.5, so N2+ has a longer bond than N2.