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JEE Advanced 2016 Paper 1 · Chemistry · Chemical Bonding and Molecular Structure · medium

Using molecular orbital theory for homonuclear diatomic species of second-period elements, choose the correct statement(s).

One or more options correct

Using molecular orbital theory for homonuclear diatomic species of second-period elements, choose the correct statement(s).
  1. A. O22−\mathrm{O_2^{2-}} has bond order 11 and is diamagnetic.
  2. B. C2\mathrm{C_2} is paramagnetic because of two unpaired electrons in π\pi orbitals.
  3. C. B2\mathrm{B_2} has bond order 22 and is diamagnetic.
  4. D. N2+\mathrm{N_2^+} has a shorter bond length than N2\mathrm{N_2}.
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Answer: A

(A) Correct. O22−\mathrm{O_2^{2-}} has 1414 valence electrons: σ2s2σ2s∗2σ2p2π2p4π2p∗4\sigma_{2s}^2\sigma_{2s}^{*2}\sigma_{2p}^2\pi_{2p}^4\pi_{2p}^{*4}, giving bond order 8−62=1\dfrac{8-6}{2}=1 with all electrons paired. (B) Incorrect. C2\mathrm{C_2} has 88 valence electrons with the π2p\pi_{2p} orbitals lying below σ2p\sigma_{2p}; the configuration σ2s2σ2s∗2π2p4\sigma_{2s}^2\sigma_{2s}^{*2}\pi_{2p}^4 has all electrons paired, bond order 22, so it is diamagnetic. (C) Incorrect. B2\mathrm{B_2} has 66 valence electrons, σ2s2σ2s∗2π2p1π2p1\sigma_{2s}^2\sigma_{2s}^{*2}\pi_{2p}^{1}\pi_{2p}^{1} with parallel spins, so bond order is 11 and it is paramagnetic. (D) Incorrect. Removing a bonding electron lowers the bond order from 33 (in N2\mathrm{N_2}) to 2.52.5, so N2+\mathrm{N_2^+} has a longer bond than N2\mathrm{N_2}.
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